diplomska naloga [univerzitetnega študijskega programa]
Nuša Hojnik (Author), Matjaž Kristl (Mentor), Mihael Drofenik (Co-mentor)

Abstract

Sonokemija je področje kemije, kjer kemijske reakcije potekajo pod vplivom zvočne energije v obliki ultrazvoka. Ultrazvok in z njimi povezani pojavi so že znani več kot sto let, njegova uporaba v kemiji pa dosega razcvet v današnjem času. Naše raziskave so temeljile na sintezah nanodelcev bakrovih sulfidov (CuS) s sonokemijsko metodo. Ta metoda se je pri sintezah pokazala kot zelo uporabna, saj so končni produkti nanokristalinični materiali. Namen raziskave je bil sintetizirati polprevodniške nanodelce bakrovega sulfida (CuS) v vodnem mediju. Pri sintezah smo uporabili direktno imerzijsko ultrazvočno sondo proizvajalca VibraCell. Pripravljene produkte smo karakterizirali z rentgensko praškovno difrakcijo (XRD) in termičnogravimetrično analizo (TGA). Da smo dosegli optimalne pogoje, smo spreminjali različne parametre, npr. topilo, vir bakra, vir žvepla, atmosfero in čas ultrazvočnega obsevanja. Zanimanje za uporabo anorganskih nanodelcev bakrovih halkogenidov se v zadnjih letih povečuje zaradi njihovih polprevodniških lastnosti, kar omogoča uporabo pri izdelavi fotoprevodniških materialov, optičnih filtrov in predvsem pri izdelavi fotocelic. Bakrovi sulfidi so zanimivi zaradi možnosti formiranja različnih nestehiometričnih spojin. Zaradi njihove kompleksne strukture in valenčnega stanja imajo nekatere unikatne lastnosti. Bakrovi sulfidi izkazujejo kovinsko prevodnost in se pri 1,6 K spremenijo v super prevodnik. Sinteza halkogenidov je v zadnjih letih precej v razvoju in dosega vedno večje zanimanje na področju optike, elektronike, fotovoltaike, medicine in drugih področjih.

Keywords

sonokemija;rentgenska praškovna difrakcija;termična analiza;nanodelci;bakrov sulfid;

Data

Language: Slovenian
Year of publishing:
Source: Maribor
Typology: 2.11 - Undergraduate Thesis
Organization: UM FKKT - Faculty of Chemistry and Chemical Engineering
Publisher: [N. Hojnik]
UDC: 544.576:549.332(043.2)
COBISS: 15370262 Link will open in a new window
Views: 2449
Downloads: 211
Average score: 0 (0 votes)
Metadata: JSON JSON-RDF JSON-LD TURTLE N-TRIPLES XML RDFA MICRODATA DC-XML DC-RDF RDF

Other data

Secondary language: English
Secondary title: Synthesis and characterization of copper sulfides by sonochemical method in aqueous solution
Secondary abstract: Sonochemistry is a filed of chemistry in which chemical reactions are critically influenced by sound energy in from of ultrasound. Ultrasound and related phenomena have been known for more than hundred years, while their use in chemistry has prospered only in recent times. Our research was based on synthesis of copper sulfides (CuS), by using the sonochemistry method. This method proved to be a very useful way of synthesis because of its final products – nanocrystal materials. The aim of the research was to synthesize semiconductor copper sulfide (CuS) in aqueous solution. For the synthesis we used direct immersion ultrasound probe made by Vibracell. The prepared products were characterized by X-Ray diffraction (XRD), thernal analysis (TGA). To achieve optimum conditions, we varied different parameters, eg. solvent, the source of copper, sulfur source, atmosphere and time of ultrasonic irradiation. In recent years, the interest in using inorganic nanoparticles of copper chalcogenides is increasing due to their semiconductor properties, allowing the use in the manufacture of photoconductive materials, optical filters and especially in the manufacture of solar cells. Copper sulfides are interesting due to their ability to form compounds with various stoichiometries. Their complex structure and valence state result in some unique properties. CuS shows metallic conductivity and transforms at 1.6 K into a superconductor. Recent syntheses of chalcogenides are in the process of development and achieves more interests in optical and electronic devices, photovoltaics, medicine and many other devices.
Secondary keywords: sonochemistry;X-Ray difraction;thermal analysis;nanoparticles;cooper sulfide;
URN: URN:SI:UM:
Type (COBISS): Undergraduate thesis
Thesis comment: Univ. v Mariboru, Fak. za kemijo in kemijsko tehnologijo
Pages: VIII, 52 f.
Keywords (UDC): mathematics;natural sciences;naravoslovne vede;matematika;chemistry;crystallography;mineralogy;kemija;physical chemistry;fizikalna kemija;chemistry of high energy processes;mathematics;natural sciences;naravoslovne vede;matematika;chemistry;crystallography;mineralogy;kemija;mineralogy;special study of minerals;sulphides;sulpho-salts;
ID: 1015638