diplomsko delo
Primož Trontelj (Author), Barbara Modec (Mentor)

Abstract

V diplomskem delu so opisane reakcije [Cu(kinal)2(MeOH)]•MeOH (kinal– = kinaldinat) z dietanolaminom (H2dea). Iz reakcijskih zmesi je na sobni temperaturi izkristalizirala enojedrna spojina cis [Cu(kinal)2(H2dea)]1/2H2dea. Pri 105 C pa je potekla deprotonacija liganda, izločeni kristali so imeli sestavo [Cu2(kinal)2(Hdea)2] (Hdea– je anionska oblika liganda). Produktov reakcij s pantenolom še nismo identificirali.

Keywords

ligand;pantenol;dietanolamin;rentgenska strukturna analiza;infrardeča spektroskopija;termogravimetrična analiza;

Data

Language: Slovenian
Year of publishing:
Typology: 2.11 - Undergraduate Thesis
Organization: UL PEF - Faculty of Education
Publisher: [P. Trontelj]
UDC: 54(043.2)
COBISS: 11760457 Link will open in a new window
Views: 2270
Downloads: 334
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Other data

Secondary language: English
Secondary title: Copper(II) coordination compounds with quinaldinate and alcoholamines
Secondary abstract: The presented work describes reactions of [Cu(kinal)2(MeOH)]•MeOH (kinal– = quinaldinate) with diethanolamine (H2dea). Reactions at room temperature afforded a mononuclear compound cis [Cu(kinal)2(H2dea)]1/2H2dea. At 105 C, deprotonation of diethanolamine took place and the composition of the crystalline product was [Cu2(kinal)2(Hdea)2] (Hdea– stands for the anionic form of the ligand). Products of the reactions with panthenol remain to be identified.
Secondary keywords: chemistry;kemija;
File type: application/pdf
Type (COBISS): Bachelor thesis/paper
Thesis comment: Univ. v Ljubljani, Pedagoška fak.
Pages: 43 str.
ID: 10869190