Andrea Cerovac (Author), Stefano Covelli (Author), Andrea Emili (Author), Elena Pavoni (Author), Elisa Petranich (Author), Asta Gregorič (Author), Janko Urbanc (Author), Enrico Zavagno (Author), Luca Zini (Author)

Abstract

This work aims at evaluating mercury (Hg) occurrence, spatial distribution and speciation in groundwater of the Isonzo/Soča River upper alluvial plain downstream from the Idrija Hg mine (Western Slovenia). Several wells and piezometers were sampled both in static and dynamic mode. On the basis of hydrochemistry and isotopic composition, the main sources of groundwater were established. Hg concentrations in the Slovenian sector, supplied by local rainfall, are comparable to values measured close to the Isonzo River. Possible further Hg local sources have been suggested. Stability field analysis for the aqueous Hg species revealed that in the presence of chloride Hg solubility may be increased by the formation of chlorocomplexes. Mercury that rarely enters reduced surrounding conditions can be bound to sulphur to form polysulphide species depending on the pH of water. Since Hg-contaminated alluvial sediments of the Isonzo River may act as a secondary Hg source in groundwater, a borehole was dug down to the water table. Mercury content and speciation revealed that cinnabar (HgS) is the prevalent form followed by the matrix-bound Hg (Hgbound). Variations of the physico-chemical boundary conditions, as well as the raising/lowering of the water table, may be locally responsible for the slight variability of Hg concentrations in the aquifer.

Keywords

aquifers;groundwater;mercury;

Data

Language: English
Year of publishing:
Typology: 1.01 - Original Scientific Article
Organization: GeoZS - Geological Survey of Slovenia
Publisher: Elsevier
UDC: 556.3
COBISS: 4978683 Link will open in a new window
ISSN: 0045-6535
Views: 84
Downloads: 54
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Other data

URN: URN:SI:UNG
Type (COBISS): Not categorized
Pages: str. 749-761
Issue: ǂVol. ǂ195
Chronology: Mar. 2018
DOI: 10.1016/j.chemosphere.2017.12.105
ID: 10892970
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