magistrsko delo
Gašper Pirc (Author), Sergej Medved (Reviewer), Milan Šernek (Mentor)

Abstract

Proučevali smo vpliv temperature stiskanja na utrjevanje urea-formaldehidnih (UF) lepil. Uporabili smo dve vrsti UF lepil proizvajalca Basf: Kaurit 345 z nižjo vsebnostjo prostega formaldehida in Kaurit 350 z višjo vsebnostjo. Preizkušanci so bili standardni in sicer iz javorjevega furnirja, debeline 0,6 mm. Preizkušanci so se po razrezu klimatizirali pri sobnih pogojih: 23 °C in 55 % vlažnostjo. Kinetiko utrjevanja UF lepil smo izvedli z ABES (Automated Bonding Evaluation System) instrumentom. Lepilna mešanica je bila skozi vse poizkuse konstantna, sestavljena iz 100 utežnih deležev vodne raztopine lepila in 1,5 % katalizatorja - amonijevega sulfata (glede na suho snov lepila). Testiranje je potekalo pri različnih temperaturah stiskanja: 80, 100, 120, 150, 170 °C. Trajanje stiskanja smo prilagajali glede na razvoj strižne trdnosti. Ko je ABES izmeril strižno trdnost večjo od 0, smo meritev pri enakem času stiskanja ponovili vsaj trikrat. Testirali smo tudi vpliv pH vrednosti različnih furnirjev na utrjevanje UF lepil. Ker katalizator zniža pH vrednost mešanice ter pospeši utrjevanje UF lepil, smo enak princip znižanja pH vrednosti ugotavljali s pomočjo različnih lesnih vrst. Vsaka lesna vrsta ima različno pH vrednost, ki tako dodatno pripomore k spremembi kislosti oz. bazičnosti lepilne mešanice med stiskanjem. Testirali smo preizkušance šestih različnih drevesnih vrst (javor, bukev, hrast, oreh, smreka, brest). S pomočjo termočlena smo raziskali spreminjanje temperature v lepilnem spoju med vročim lepljenjem. Ugotovili smo, da je imela temperatura stiskanja bistveni vpliv na hitrost utrjevanja lepila in da hlajenje preizkušanca po stiskanju ni vplivalo na trdnost spoja. Lepilo z višjim deležem formaldehida je utrjevalo hitreje.

Keywords

DGST;ABES;UF lepilo;Kaurit 345;Kaurit 350;urea-formaldehid;lepila;katalizator;furnir;vroče stiskanje;pH lesa;javor;bukev;hrast;oreh;smreka;brest;

Data

Language: Slovenian
Year of publishing:
Typology: 2.09 - Master's Thesis
Organization: UL BF - Biotechnical Faculty
Publisher: [G. Pirc]
UDC: 630*824.8
COBISS: 3065737 Link will open in a new window
Views: 555
Downloads: 209
Average score: 0 (0 votes)
Metadata: JSON JSON-RDF JSON-LD TURTLE N-TRIPLES XML RDFA MICRODATA DC-XML DC-RDF RDF

Other data

Secondary language: English
Secondary title: Influence of pressing temperature on dynamics of strength of adhesive bond
Secondary abstract: We studied the effect of pressing temperature on hardening of urea-formaldehyde (UF) adhesives. We used two types of UF adhesives pre-prepared by manufacturer Basf: Kaurit 345 with a lower content of free formaldehyde and Kaurit 350 with a higher content. For testing of kinetics, we used ABES (Automated Bonding Evaluation System) instrument. To preform standard tests, we used maple veneers, with thickness of 0,6 mm. All veneer was prepared and then left for two day at room conditions of 23 °C and 55 % air humidity, to acclimate. Every test has constant adhesive mixture, consisted of 100 weight units of aqueous adhesive solution and 1,5 % catalyst (ammonium sulphate) (according to dry quantity of glue). Bonding strength was investigated at different pressing temperatures: 80, 100, 120, 150 and 170 °C. Times of gluing were adjusted according to feedback of shear strength. If ABES measured sear strength higher than 0 N/mm2, we carried out at least two more tests of strength. pH value of wood was measured. With usage of different veneers, we tested its influence on bond development. For this test, we used six different species (maple, beech, oak, walnut, spruce, elm). With use of thermocouple we investigated temperature changes in bond during gluing process. We found out that the pressing temperature had a significant influence on hardening time. Cooling specimens after gluing process did not have big effect on joint strength. Adhesive with more formaldehyde was curing faster.
Secondary keywords: DGST;ABES;UF glue;Kaurit 345;Kaurit 350;urea-formaldehide;wood glues;catalyst;veneer;hot press;wood pH;maple;beech;oak;walnut;spruce;elm;
Type (COBISS): Master's thesis/paper
Study programme: 0
Embargo end date (OpenAIRE): 1970-01-01
Thesis comment: Univ. v Ljubljani, Biotehniška fak., Oddelek za lesarstvo
Pages: X, 46 f.
ID: 11162705