Adsorpcija ionov težkih kovin na zeolit

diplomsko delo visokošolskega strokovnega študijskega programa I. stopnje

Urban Šket (Author), Mojca Škerget (Mentor), Maja Čolnik (Co-mentor)

Abstract

Diplomsko delo je rezultat preučevanja adsorpcije težkih ionov Pb2+, Cu2+ in Fe2+ na zeolit. Ker so ti ioni zelo močni onesnaževalci okolja, se pojavlja vprašanje kako zaščititi naravo pred njihovimi škodljivimi vplivi. Ena iz med možnosti je adsorpcija ionov na močen adsorbent, kar je v našem primeru zeolit. Tako je bistveno, da dobro spoznamo zeolit, preučimo njegovo strukturo in lastnosti, ter nato z različnimi kemijskimi analizami določimo, kakšne zmožnosti adsorpcije ima zeolit. Namen diplomske naloge je bil določiti adsorpcijske lastnosti zeolita v raztopini za adsorpcijo ionov težkih kovin ( Cu2+, Fe2+, Pb2+ ), določiti masne koncentracije kovinskih ionov z optično emisijsko spektroskopijo (ICP OES), ter preučiti specifiko samega zeolita (zeta potencial, specifična površina, velikost delcev). Za ugotavljanje adsopcijskih lastnosti zeolita smo spreminjali dva ključna parametra, koncentracijo raztopine težkih ionov, ter pH raztopine. S spreminjanjem teh parametrov smo prišli do ugotovitve, da so najbolj optimalni pogoji za adsorpcijo pri koncentraciji 13 mM in pri pH vrednosti 7. S preiskovanjem vpliva koncentracije težkih ionov na adsorbent smo ugotovili, da uspešnost adsorpcije pri višji koncentraciji upada, izjema je le baker. Pri spreminjanju pH vrednosti, pa se je izkazalo, da pH nima takšen velik vpliv na adsorpcijo kot jo ima koncentracija, saj smo ugotovili, da se adsorpcijska sposobnost malo zmanjša le pri zelo nizki pH vrednosti ( pH = 2,5 ). Ugotavljali smo tudi medsebojni vpliv ionov na učinkovitost adsorpcije ionov na zeolit, pri čemer se je izkazalo, da mešanica ionov v raztopini dobro vpliva na adsorpcijo, saj je bila v našem primeru učinkovitost adsorpcije za vse tri ione nad 99%.

Keywords

adsorpcija;zeolit;ioni težkih kovin;zeta potencial;koncentracija;pH raztopine;diplomske naloge;

Data

Language:	Slovenian
Year of publishing:	2019
Typology:	2.11 - Undergraduate Thesis
Organization:	UM FKKT - Faculty of Chemistry and Chemical Engineering
Publisher:	[U. Šket]
UDC:	66.081:661.183.6(043.2)
COBISS:	22691606
Views:	607
Downloads:	73
Average score:	0 (0 votes)
Metadata:

Other data

Secondary language:	English
Secondary title:	Adsorption of heavy metal ions on zeolite
Secondary abstract:	The diploma thesis is the result of studying the adsorption of heavy metal ions of Pb2+, Cu2+ and Fe2+ on zeolite. Since this ions are very powerful pollutants of the environment, the question arises as how to protect nature from their harmful effects. One of the possibilities is the adsorption of ions on a strong adsorbent, which in our case is zeolite. It is essential to get to know the zeolite well, to study its structure and properties, and then to determine, through various chemical analyzes, what is the zeolite's adsorption capacity. The purpose of this thesis was to determine the adsorption properties of zeolit for adsorption of heavy metal ions (Cu2+, Fe2+, Pb2+) in solution, to determine the mass concentrations of metal ions by optical emission spectroscopy (ICP OES), and to study the specificity of the zeolite itself (zeta potential, specific surface area, particle size). In order to determine the adsorption properties of zeolite, two key parameters, the concentration of the heavy metal ions in solution and the pH of the solution, have been studied. By changing these parameters, the most optimal conditions for adsorption were determined at a concentration of 13 mM and at a pH value of 7. By examining the influence of the concentration of heavy metal ions on the adsorbent, we found that the adsorption efficiency at a higher concentration decreases, with the exception of copper. When changing the pH value, it turned out that pH did not have as much effect on adsorption as the concentration, since we found that the adsorption efficiency decreased only at very low pH (pH = 2.5). We also investigated the interaction of ions on the adsorption efficiency of the zeolite, which showed that the mixture of ions in solution had a good effect on adsorption, since in our case the adsorption efficiency for all three ions was above 99%.
Secondary keywords:	Adsorption;zeolite;heavy metal ions;zeta potential;concentration;pH of the aqueous solution;
Type (COBISS):	Bachelor thesis/paper
Thesis comment:	Univ. v Mariboru, Fak. za kemijo in kemijsko tehnologijo
Pages:	IX, 23 str.
ID:	11214857