ǂa ǂstudy of 5p hydrides
Robert Hauko (Author), Jana Padežnik Gomilšek (Author), Alojz Kodre (Author), Iztok Arčon (Author)

Abstract

An absorption cell is constructed for x-ray absorption spectroscopy of reactive, unstable or hazardous gases at room temperature. In conjunction with in-situ micro-synthesis technique relying on handling the gas in syringes it enabled a first measurement of x-ray absorption spectra in the region of K and L edges for the series of hydrides of 5p elements (SnH4, SbH3, TeH2, HI). The signal-to-noise ratio above 103 was achieved, whereby fine detail is discerned in the spectra, in particular the small sharp features above each absorption edge, testifying of coexcitations of outer electrons in the core photoeffect.

Keywords

X-ray absorption spectroscopy;micro-synthesis absorption cell;gaseous hydrides;multielectron photoexcitations;

Data

Language: English
Year of publishing:
Typology: 1.01 - Original Scientific Article
Organization: UNG - University of Nova Gorica
UDC: 54
COBISS: 5564411 Link will open in a new window
ISSN: 0969-806X
Views: 2645
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Other data

URN: URN:SI:UNG
Type (COBISS): Not categorized
Pages: str. 1-4
Issue: ǂVol. ǂ171
Chronology: Jun. 2020
DOI: 10.1016/j.radphyschem.2020.108743
ID: 11404459
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