diplomsko delo
Luka Setnikar (Author), Franc Perdih (Mentor)

Abstract

Sintetiziral sem spojino [Zn(I3O)2(H2O)2] iz ZnCl2 in indol-3-ocetne kisline, ki sem jo nato uporabil pri nadaljnjih pretvorbah z uporabo štirih različnih nevtralnih dušikovih ligandov (bipy = 2,2'-bipiridin, phen = fenantrolin, bipyam = bipiridinamin, 4 ampy = 4-aminopiridin) v razmerjih 1:1 ob uporabi različnih topil (metanol, etanol, kloroform). Nastale produkte [Zn(I3O)2(bipy)], [Zn(I3O)2(phen)], [Zn(I3O)2(bipyam)] in [Zn(I3O)2(4-ampy)2]∙H2O sem analiziral in okarakteriziral z IR spektroskopijo, rentgensko praškovno analizo (PXRD), elementno analizo (CHN), ter posnel UV-Vis in luminiscenčne spektre v trdnem. Produkte [Zn(I3O)2(bipy)], [Zn(I3O)2(bipyam)] in [Zn(I3O)2(4-ampy)2]∙H2O sem okarakteriziral tudi z jedrsko magnetno resonanco (1H NMR).

Keywords

koordinacijske spojine;sinteza;cink;nevtralni dušikovi ligandi;karakterizacija;luminiscenca;diplomske naloge;

Data

Language: Slovenian
Year of publishing:
Typology: 2.11 - Undergraduate Thesis
Organization: UL FKKT - Faculty of Chemistry and Chemical Technology
Publisher: [L. Setnikar]
UDC: 546.47(043.2)
COBISS: 21916675 Link will open in a new window
Views: 629
Downloads: 151
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Other data

Secondary language: English
Secondary title: Luminescence properties of zinc coordination compounds with indole-3-carboxylate ligand
Secondary abstract: The starting compound [Zn(I3O)2(H2O)2] was synthesized by the reaction of ZnCl2 and indol-3-acetic acid, which was used as the starting compound for the synthesis of four different zinc complex by adding four different neutral nitrogen-donor ligands in 1:1 ratio with the starting compound in different solvents. The four resulting compounds [Zn(I3O)2(bipy)], [Zn(I3O)2(phen)], [Zn(I3O)2(bipyam)] in [Zn(I3O)2(4-ampy)2]∙H2O (bipy = bipiridin, phen = fenantrolin, bipyam = bipiridinamin, 4 ampy = 4-aminopiridin) have been analysed and characterized by some analytical methods such as: IR spectroscopy, X-ray diffraction (PXRD), nuclear magnetic resonance spectroscopy (1H NMR), CHN elemental analysis as well as UV-Vis and luminescence in the solid-state.
Secondary keywords: zink;indol-3-carboxylate;bipy;phen;bipyam;4-ampy;UV-Vis;Luminiscenc;
Type (COBISS): Bachelor thesis/paper
Study programme: 1000374
Embargo end date (OpenAIRE): 1970-01-01
Thesis comment: Univ. v Ljubljani, Fak. za kemijo in kemijsko tehnologijo, VSŠ Kemijska tehnologija
Pages: 37 f.
ID: 11841685