diplomsko delo
Lavra Kos (Author), Andrej Pevec (Mentor)

Abstract

Pripravila sem adeninijev hekasfluoridotitanat(IV), to je sol s formulo [RH2][TiF6] (1), pri čemer je R adenin (C5H5N5). Spojino sem sintetizirala v stehiometričnem razmerju 1:1 med titanovim dioksidom in adeninom v fluorovodikovi kislini. Iz raztopine se je izločil kristalinični produkt, ki sem ga nato karakterizirala z metodo rentgenske strukturne analize. Opisala sem tudi tri podobne spojine iz literature, ki vsebujejo dvakrat protoniran adeninijev kation in oktaedrični heksahalogenidometalatni anion s formulami: [RH2]2[SnCl6]Cl2∙4H2O (2), [RH2]2[ReCl6]Cl2∙4H2O (3) in [RH2]2[ReBr6]Br2∙4H2O (4).

Keywords

titanov dioksid;adenin;heksafluoridotitanat(IV);kristalna struktura;rentgenska strukturna analiza;diplomske naloge;

Data

Language: Slovenian
Year of publishing:
Typology: 2.11 - Undergraduate Thesis
Organization: UL FKKT - Faculty of Chemistry and Chemical Technology
Publisher: [L. Kos]
UDC: 546.824(043.2)
COBISS: 37300739 Link will open in a new window
Views: 425
Downloads: 139
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Other data

Secondary language: English
Secondary title: ADENINE AS A CATION IN HEXAFLUORIDOTITANATE SALTS
Secondary abstract: I have prepared adenine hexafluoridotitanate(IV) salt, with a general formula [RH2][TiF6] (1) in which R means adenine. I synthesized the compound in stoichiometric ratio 1:1 between titanium dioxide and adenine in HF acid. The obtained product was crystalline and was then characterized with X-ray structure analysis. I have also described three similar already known compounds that contain doubly protonated adenine cation and octahedral anion with formulas: [RH2]2[SnCl6]Cl2∙4H2O (2), [RH2]2[ReCl6]Cl2∙4H2O (3) in [RH2]2[ReBr6]Br2∙4H2O (4).
Secondary keywords: hexafluoridotitanate(IV);adeninium;crystal structure;
Type (COBISS): Bachelor thesis/paper
Study programme: 1000374
Embargo end date (OpenAIRE): 1970-01-01
Thesis comment: Univ. v Ljubljani, Fak. za kemijo in kemijsko tehnologijo, VSŠ Kemijska tehnologija
Pages: 30 str.
ID: 12072141