magistrsko delo
Uroš Rapuš (Author), Jakob Kljun (Mentor), Franc Požgan (Thesis defence commission member), Iztok Turel (Thesis defence commission member)

Abstract

Sintetizirana je bila serija substituiranih pirimidinov iz acetil heteroaromatov, nato je bila izvedena metilacija pripravljenih spojin. Pri tem je prišlo do nastanka dveh različnih tipov produktov. Vse pripravljene spojine so bile uporabljene kot ligandi za sintezo renijevih koordinacijskih spojin. Vsi produkti so bili karakterizirani z jedrsko magnetno resonanco (NMR), masno spektrometrijo, IR spektroskopijo in elementno analizo CHN. Pripravljeni so bili tudi monokristali nekaterih spojin, katerim je bila določena struktura z rentgensko difrakcijo.

Keywords

koordinacijske spojine;renij;kelatni ligandi;substituirani pirimidini;metiliranje;žveplo;magistrska dela;

Data

Language: Slovenian
Year of publishing:
Typology: 2.09 - Master's Thesis
Organization: UL FKKT - Faculty of Chemistry and Chemical Technology
Publisher: [U. Rapuš]
UDC: 546.719:547.85(043.2)
COBISS: 76782851 Link will open in a new window
Views: 317
Downloads: 97
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Other data

Secondary language: English
Secondary title: Synthesis of 4-heteroaryl substituted pyrimidines and their coordination compounds
Secondary abstract: A series of substituted pyrimidines were synthesized from acetyl substituted heteroaromatics. Methylation of the prepared compounds was then carried out and two different types of products were isolated. All the prepared compounds were used as ligands in the synthesis of rhenium coordination compounds. All products were characterized by nuclear magnetic resonance (NMR), mass spectrometry, IR spectroscopy and elemental analysis CHN. For some compounds, monocrystals were obtained and their molecular structures were determined by X-ray diffraction.
Secondary keywords: substituted pyrimidines;sulphur;methylation;rhenium;
Type (COBISS): Master's thesis/paper
Study programme: 1000375
Embargo end date (OpenAIRE): 1970-01-01
Thesis comment: Univ. v Ljubljani, Fak. za kemijo in kemijsko tehnologijo, smer Kemija
Pages: 105 str.
ID: 13299907