diplomsko delo
Tanja Vidic (Author), Bojan Kozlevčar (Mentor)

Abstract

Opisanih je pet spojin {[Cu(L)(nia)2]•H2O}n 1, {[Cu(L)(3-apy)2]•(H2L)}n 2, [(Cu(N3)(H2O))2(L)]n 3, [Cu(L)(H2O)2]n 4 in [Cu3(L)2(OH)2(H2O)4]n 5 v sistemu bakrovih(II) spojin s koordiniranim anionom adipinske kisline (C6H10O4 = H2L) in dodatnim dušikovim ligandom. Spojinam so določili kristalne strukture ter z elementno analizo določili ujemanje eksperimentalnih vrednosti z izračunanimi vrednostmi teoretične sestave za posamezno spojino. Vse spojine so polimerne. Povsod je mostovni ligand adipinat. Prisotnost ligandov se sklada z IR spektri, magnetne lastnosti z Cu(II) ter elektronski spektri z barvami spojin.

Keywords

koordinacijske spojine;baker(II);ligandi;adipinska kislina;struktura spojin;IR spektroskopija;diplomske naloge;

Data

Language: Slovenian
Year of publishing:
Typology: 2.11 - Undergraduate Thesis
Organization: UL FKKT - Faculty of Chemistry and Chemical Technology
Publisher: [T. Vidic]
UDC: 546.562:547.461.6(043.2)
COBISS: 76833539 Link will open in a new window
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Downloads: 35
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Other data

Secondary language: English
Secondary title: Copper(II) compounds with adipic acid and nitrogen donor ligands
Secondary abstract: Five compounds, namely {[Cu(L)(nia)2]•H2O}n 1, {[Cu(L)(3-apy)2]•(H2L)}n 2, [(Cu(N3)(H2O))2(L)]n 3, [Cu(L)(H2O)2]n 4 and [Cu3(L)2(OH)2(H2O)4]n 5 in a system of copper(II) compounds with a coordinated anion of adipic acid (C6H10O4 = H2L) along with additional nitrogen ligand are described. The crystal structures were determined for the compounds and the matching of the experimental values with the calculated ones of the theoretical composition for each compound was determined by elemental analysis. All compounds are polymeric. Adipinate ligand herein always serves as a bridging ligand. The ligand presence is in accordance with the IR spectra. Their magnetic properties agree with Cu(II) and the electronic spectra with the compounds' colours.
Secondary keywords: copper(II);adipic acid;structure of compounds;IR spectroscopy;
Type (COBISS): Bachelor thesis/paper
Study programme: 1000374
Embargo end date (OpenAIRE): 1970-01-01
Thesis comment: Univ. v Ljubljani, Fak. za kemijo in kemijsko tehnologijo
Pages: 34 str.
ID: 13328267