diplomsko delo
Alenka Golub (Author), Iztok Turel (Mentor)

Abstract

V diplomskem delu sem povzela do zdaj znane pomembnejše lastnosti bizmuta in kako se ta uporablja v medicini. V strokovni literaturi sem pregledala strukture in sintezne postopke bizmutovih kompleksov z 2,2´-bipiridinom in 1,10-fenantrolinom kot modelnima ligandoma. Pri tem sem se osredotočila na spojine s halogenidnimi in nitratnimi ligandi. V eksperimentalnem delu sem nekatere od sintez skušala ponoviti z 2,2´-bipiridinom. Cilj diplomske naloge je bil poskus izvedbe lažjih sinteznih postopkov iz strokovne literature z izbranim piridin-4,5-dikarboksilatnim estrom sintetiziranim v laboratoriju. Reakcije sem izvedla z bizmutovim kloridom in bizmutovim nitratom. Produkte sem karakterizirala z metodami masne spektrometrije visoke ločljivosti (HRMS), 1H NMR spektroskopijo in UV-Vis spektroskopijo.

Keywords

koordinacijske spojine;bizmut;ligandi;bipiridin;piridin-4,5-dikarboksilatni ester;analiza strukture;diplomske naloge;

Data

Language: Slovenian
Year of publishing:
Typology: 2.11 - Undergraduate Thesis
Organization: UL FKKT - Faculty of Chemistry and Chemical Technology
Publisher: [A. Golub]
UDC: 546.87:547.82(043.2)
COBISS: 78807299 Link will open in a new window
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Downloads: 31
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Other data

Secondary language: English
Secondary title: Analysis of synthetic procedures and structures of bismuth coordination compounds with nitrogen-binding ligands and planning of synthetic analog compounds with pyridine dicarboxylate esters
Secondary abstract: In my thesis, I summarized so far known important characteristics of bismuth and how it is used in medicine. In the professional literature, I have reviewed the structures and synthetic procedures of bismuth complexes with 2,2´-bipyridine and 1,10-phenanthroline as model ligands. I focused on compounds with halogenido and nitrato ligands. In the experimental part, I tried to repeat some of the syntheses with 2,2´-bipyridine. The thesis aimed to perform some of the easier synthetic procedures from the scientific literature with a selected pyridine-4,5-dicarboxylate ester synthesized in the laboratory. I performed the reactions with bismuth chloride and bismuth nitrate. The products were characterized by high-resolution mass spectrometry (HRMS), 1H NMR spectroscopy and UV-Vis spectroscopy.
Secondary keywords: bismuth;bipyridine;pyridine-4,5-dicarboxylate ester;
Type (COBISS): Bachelor thesis/paper
Study programme: 1000374
Embargo end date (OpenAIRE): 1970-01-01
Thesis comment: Univ. v Ljubljani, Fak. za kemijo in kemijsko tehnologijo, VSŠ Kemijska tehnologija
Pages: 37 str.
ID: 13328277