diplomsko delo
Nika Šinkovec (Author), Andrej Pevec (Mentor)

Abstract

V diplomskem delu so predstavljene kristalne strukture štirih koordinacijskih spojin, ki sestojijo iz bipiridinijevega kationa ter heksafluoridometalatnega aniona. Predstavljene so spojine: 2,2'-bipiridinijev heksafluoridotitanat, 4,4'-bipiridinijev heksafluoridotitanat, 4,4'-bipiridinijev heksafluridostanat ter 4,4'-bipiridinijev heksafluoridohafnat. V primeru 2,2'-bipiridinijevega heksafluoridotitanata je protoniran samo en dušikov atom v 2,2'-bipiridinijevem kationu, v ostalih treh spojinah pa sta v 4,4'-bipiridinijevih kationih protonirana oba dušikova atoma. V diplomski nalogi sem se osredotočila na sintezno pot ter rezultate rentgenske strukturne analize posamezne spojine.

Keywords

bipiridin;heksafluoridometalati;rentgenska strukturna analiza;diplomske naloge;

Data

Language: Slovenian
Year of publishing:
Typology: 2.11 - Undergraduate Thesis
Organization: UL FKKT - Faculty of Chemistry and Chemical Technology
Publisher: [N. Šinkovec]
UDC: 544.022.51(043.2)
COBISS: 100573443 Link will open in a new window
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Downloads: 19
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Other data

Secondary language: English
Secondary title: CRYSTAL STRUCTURES OF BIPYRIDINIUM HEXAFLUORIDOMETALLATES
Secondary abstract: The diploma thesis presents the crystal structures of four coordination compounds, consisting of a bipyridinium cation and a hexafluoridometallate anion. The following compounds are presented: 2,2’-bipyridinium hexafluoridotitanate, 4,4’-bipyridinium hexafluoridotitanate, 4,4’-bipyridinium hexafluoridostanate and 4,4’-bipyridinium hexafluoridohafnate. In the case of 2,2’-bipyridinium hexafluoridotitanate, only one nitrogen atom in the 2,2’-bipyridinium cation is protonated, and in the other three compounds both nitrogen atoms are protonated in the 4,4’-bipyridinium cations. In my thesis, I focused on the synthesis pathway and the results of X-ray structural analysis of each compound.
Secondary keywords: crystal structure;bipyridine;hexafluoridometallates;X-ray crystallography;Kristalna struktura;Univerzitetna in visokošolska dela;
Type (COBISS): Bachelor thesis/paper
Study programme: 1000374
Thesis comment: Univ. v Ljubljani, Fak. za kemijo in kemijsko tehnologijo, VSŠ Kemijska tehnologija
Pages: 28 str.
ID: 14720667