Matevž Kunaver (Author), Mark Žic (Author), Iztok Fajfar (Author), Tadej Tuma (Author), Arpad Bürmen (Author), Vanja Subotić (Author), Žiga Rojec (Author)

Abstract

Electrochemical impedance spectroscopy (EIS) is an important electrochemical technique that is used to detect changes and ongoing processes in a given material. The main challenge of EIS is interpreting the collected measurements, which can be performed in several ways. This article focuses on the electrical equivalent circuit (EEC) approach and uses grammatical evolution to automatically construct an EEC that produces an AC response that corresponds to one obtained by the measured electrochemical process(es). For fitting purposes, synthetic measurements and data from measurements in a realistic environment were used. In order to be able to faithfully fit realistic data from measurements, a new circuit element (ZARC) had to be implemented and integrated into the SPICE simulator, which was used for evaluating EECs. Not only is the presented approach able to automatically (i.e., with almost no user input) produce a more than satisfactory EEC for each of the datasets, but it also can also generate completely new EEC configurations. These new configurations may help researchers to find some new, previously overlooked ongoing electrochemical processes.

Keywords

elektrokemična impedančna spektroskopija;gorivne celice;optimizacija;evolucijsko računanje;electrochemical impedance spectroscopy;fuel cells;optimization;evolutionary computation;

Data

Language: English
Year of publishing:
Typology: 1.01 - Original Scientific Article
Organization: UL FE - Faculty of Electrical Engineering
UDC: 621.39:543.42
COBISS: 81932291 Link will open in a new window
ISSN: 2227-9717
Views: 94
Downloads: 36
Average score: 0 (0 votes)
Metadata: JSON JSON-RDF JSON-LD TURTLE N-TRIPLES XML RDFA MICRODATA DC-XML DC-RDF RDF

Other data

Secondary language: Slovenian
Secondary keywords: elektrokemična impedančna spektroskopija;gorivne celice;optimizacija;evolucijsko računanje;
Type (COBISS): Article
Pages: str. 1-17
Volume: ǂiss. ǂ11
Issue: 1859
Chronology: Nov. 2021
DOI: 10.3390/pr9111859
ID: 15088783