Juan Reyes-Herrera (Author), Damaris Acosta-Slane (Author), Hiram Castillo Michel (Author), Ana E. Pradas del Real (Author), Katarina Vogel-Mikuš (Author), Federico Benetti (Author), Marco Roman (Author), Julie Villanova (Author), M. Cecilia Valles-Aragón (Author)

Abstract

TiO$_2$ nanoparticles (TiO$_2$-NPs) have a wide range of industrial applications (paintings, sunscreens, food and cosmetics) and is one of the most intensively used nanomaterials worldwide. Leaching from commercial products TiO$_2$-NPs are predicted to significantly accumulate in wastewater sludges, which are then often used as soil amendment. In this work, sludge samples from four wastewater treatment plants of the Chihuahua State in Mexico were obtained during spring and summer (2017). A comprehensive characterization study was performed by X-ray based (laboratory and synchrotron) techniques and electron microscopy. Ti was detected in all sludge samples (1810–2760 mg/kg) mainly as TiO$_2$ particles ranging from 40 nm up to hundreds of nm. MicroXANES data was analyzed by principal component analysis and linear combination fitting enabling the identification of three predominant Ti species: anatase, rutile and ilmenite. Micro-XANES from the smaller Ti particles was predominantly anatase (68% + 32% rutile), suggesting these TiO$_2$-NPs originate from paintings and cosmetics. TEM imaging confirmed the presence of nanoscale Ti with smooth surface morphologies resembling engineered TiO$_2$-NPs. The size and crystalline phase of TiO$_2$-NPs in the sludge from this region suggest increased reactivity and potential toxicity to agro-systems. Further studies should be dedicated to evaluating this.

Keywords

nanoparticles;sewage sludge;X-ray microspectroscopy;synchrotron;

Data

Language: English
Year of publishing:
Typology: 1.01 - Original Scientific Article
Organization: UL BF - Biotechnical Faculty
UDC: 549.514.6
COBISS: 98738179 Link will open in a new window
ISSN: 2079-4991
Views: 101
Downloads: 24
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Other data

Type (COBISS): Article
Pages: str. 1-21
Volume: ǂVol. ǂ12
Issue: ǂiss. ǂ5
Chronology: 2022
DOI: 10.3390/nano12050744
ID: 15584951