Mohanachandran Nair Sindhu Swapna (Author), H. V. Saritha Devi (Author), G. Ambadas (Author), Sankaranarayana Iyer Sankararaman (Author)

Abstract

The process of functionalization of metals in natural carbon matrices has become an important area of research due to its improved properties and applications. Carbon materials possessing photoluminescence (PL) properties find a wide range of applications in photonics. Among the various carbon materials available in nature, cellulose has critical importance since it is the most abundant and wide-spread biopolymer on Earth, and also, the important component in plants’ skeleton. In the present work, the functionalized carbonaceous material is prepared by the hydrothermal treatment of natural cellulosic source Aloe Vera and the metallic element sodium is properly incorporated into it by adding sodium borohydride to observe the fluorescence emission changes. The incorporation of metal ions in the carbon matrix leads to structural modifications and properties as evidenced by field emission scanning electron microscopy, Energy dispersive spectroscopy, X-ray dot mapping, X-ray Photoelectron spectroscopy, and X-ray diffraction analysis. The optical emission characteristics are studied using Photoluminescence spectroscopy, CIE plot, power spectrum, color purity, and quantum yield. The excitation wavelength dependent photoluminescence emission mechanism shown by the carbon–metal incorporated products obtained from the cellulosic raw materials makes them suitable for biomedical and biosensing applications because of the non-toxic and eco-friendly nature.

Keywords

fluorescent emission;sodium carbide;cellulose;carbon matrix;

Data

Language: English
Year of publishing:
Typology: 1.01 - Original Scientific Article
Organization: UNG - University of Nova Gorica
UDC: 620.1/.2
COBISS: 113431043 Link will open in a new window
ISSN: 0957-4522
Views: 503
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Other data

URN: URN:SI:UNG
Type (COBISS): Not categorized
Pages: str. 508-517
Volume: ǂVol. ǂ30
Issue: ǂiss. ǂ1
Chronology: 2019
DOI: 10.1007/s10854-018-0316-2
ID: 15786696