diplomsko delo
Lara Rebolj (Author), Barbara Modec (Mentor)

Abstract

V diplomskem delu so opisane reakcije dveh izhodnih spojin cinka(II) s pikolinsko kislino in piperidinom. Uporabljeni izhodni spojini sta bili cinkov oksid in cinkov klorid. Reakcije so bile narejene pri sobni temperaturi, pri pogoju refluksa v acetonitrilu in segrevanju pri 105 °C v avtoklavu. Iz reakcijskih zmesi so bili izolirani trdni produkti, ki so potrdili nastanek amidina iz piperidina in acetonitrila pri opisanih reakcijskih pogojih. Izolirani trdni produkti so bili: piperidinijev klorid, pipeH[Zn(pic)3]·1,5H2O, amidinijev klorid, pipeamH[Zn(pic)3]·0,5H2O in [Zn(NH3)4]SO4·H2O.

Keywords

cink(II);ligandi;pikolinat;pikolinska kislina;piperidin;amidin;diplomske naloge;

Data

Language: Slovenian
Year of publishing:
Typology: 2.11 - Undergraduate Thesis
Organization: UL FKKT - Faculty of Chemistry and Chemical Technology
Publisher: [L. Rebolj]
UDC: 546.47(043.2)
COBISS: 120803843 Link will open in a new window
Views: 33
Downloads: 15
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Other data

Secondary language: English
Secondary title: Coordination compounds of zinc(II) with picolinate and piperidine
Secondary abstract: The diploma work describes reactions of two zinc(II) starting materials with picolinic acid and piperidine. Zinc oxide and zinc chloride were used as the starting materials. The reactions were carried out at ambient conditions, by heating in refluxing acetonitrile or at 105 °C in autoclaves. The isolated solids confirmed the formation of amidine from piperidine and acetonitrile under given conditions. The obtained products were: piperidinium chloride, pipeH[Zn(pic)3]·1,5H2O, amidinium chloride, pipeamH[Zn(pic)3]·0,5H2O and [Zn(NH3)4]SO4·H2O.
Secondary keywords: zinc(II);picolinate;piperidine;amidine;coordination compounds;Koordinacijske spojine;Univerzitetna in visokošolska dela;
Type (COBISS): Bachelor thesis/paper
Study programme: 1000374
Embargo end date (OpenAIRE): 1970-01-01
Thesis comment: Univ. v Ljubljani, Fak. za kemijo in kemijsko tehnologijo, VSŠ Kemijska tehnologija
Pages: 29 str.
ID: 16270681