diplomsko delo
Erik Črešnovar (Author), Barbara Modec (Mentor)

Abstract

Enojedrno koordinacijsko spojino bakra(II) s kinaldinatom, [Cu(quin)2(H2O)], smo pri različnih pogojih reagirali z dvema alkoholaminoma, dietanolaminom (deaH2) in N-metildietanolaminom (Me-deaH2). V obeh primerih sta nastali dvojedrni spojini, v primeru dietanolamina [Cu2(quin)2(deaH)2)], v primeru N-metildietanolamina pa [Cu2(quin)3(Me-deaH)]·2MeOH. Na bakrove(II) ione je koordinirana anionska oblika alkoholamina, ki nastane z deprotonacijo hidroksilne skupine. Preučevali smo vpliv reakcijskih pogojev in topilnega sistema na naravo produktov.

Keywords

koordinacijska kemija;alkoholamini;dietanolamin;N-metildietanolamin;diplomske naloge;

Data

Language: Slovenian
Year of publishing:
Typology: 2.11 - Undergraduate Thesis
Organization: UL FKKT - Faculty of Chemistry and Chemical Technology
Publisher: [E. Črešnovar]
UDC: 546.562:547.233(043.2)
COBISS: 153290499 Link will open in a new window
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Downloads: 32
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Other data

Secondary language: English
Secondary title: Dinuclear copper(II) complexes with alcoholamines
Secondary abstract: Mononuclear copper(II) complex with quinaldinate, [Cu(quin)2(H2O)], was reacted with two alcoholamines, diethanolamine (deaH2) and N-methyldiethanolamine (Me-deaH2). Reaction conditions were also varied. Dinuclear copper(II) complexes were obtained for both ligand systems, [Cu2(quin)2(deaH)2)] for diethanolamine and [Cu2(quin)3(Me-deaH)]·2MeOH for N-methyldiethanolamine. Anionic forms of alcoholamines were found coordinated to copper(II) ions. The anions form on the deprotonation of hydroxyl moiety. Influence of the reaction conditions over the nature of the product was also studied.
Secondary keywords: copper(II);coordination chemistry;alcoholamines;Koordinacijske spojine;Baker;Univerzitetna in visokošolska dela;
Type (COBISS): Bachelor thesis/paper
Study programme: 1000374
Embargo end date (OpenAIRE): 1970-01-01
Thesis comment: Univ. v Ljubljani, Fak. za kemijo in kemijsko tehnologijo, VSŠ Kemijska tehnologija
Pages: 20 str.
ID: 18721691