diplomsko delo
Blaž Antonin (Author), Jakob Kljun (Mentor)

Abstract

Pripravil sem pet bakrovih(I) kompleksov z ligandi bipiridinskega tipa. V prvem setu spojin so se (metiltio)pirimidinski ligandi na centralni ion vezali v stehiometričnem razmerju 2:1. Poleg kelatnega liganda pa je en kompleks vseboval še trifenilfosfin. Izkaže se, da reakcija tega tipa z drugimi uporabljenimi pirimidintioni ne poteče. Dobljene spojine sem okarateriziral z NMR, UV-VIS in IR spektroskopijo, masno spektrometrijo in CHN elementno analizo. Pripravil sem tudi monokristale večine kompleksov. Njihova struktura je bila določena z rentgensko difrakcijo.

Keywords

baker(I);ligandi;substituirani pirimidini;sinteza;diplomska dela;

Data

Language: Slovenian
Year of publishing:
Typology: 2.11 - Undergraduate Thesis
Organization: UL FKKT - Faculty of Chemistry and Chemical Technology
Publisher: [B. Antonin]
UDC: 546.56:547.85(043.2)
COBISS: 163791363 Link will open in a new window
Views: 13
Downloads: 4
Average score: 0 (0 votes)
Metadata: JSON JSON-RDF JSON-LD TURTLE N-TRIPLES XML RDFA MICRODATA DC-XML DC-RDF RDF

Other data

Secondary language: English
Secondary title: Synthesis and characterization of copper(I) complexes with chelating 2-(methylthio)pyrimidines
Secondary abstract: I have prepared five copper(I) complexes with bipyridine-type ligands. In the first set of compounds (methyltio)pyrimidine ligands have been bound to central ion in stochiometric ratio 2:1. In addition to chelate ligand one complex also contained triphenylphosphine. As it turns out, similar reactions with other used pyrimidinthiones do not take place. Prepared compounds were characterised with NMR, UV-VIS and IR spectroscopy, mass spectrometry and CHN elemental analysis. I have also prepared monocrystals of most complexes, structures of which were determined with X-ray diffraction.
Secondary keywords: copper(I);coordination compounds;substituted pyrimidines;synthesis;Koordinacijske spojine;Univerzitetna in visokošolska dela;
Type (COBISS): Bachelor thesis/paper
Study programme: 1000373
Thesis comment: Univ. v Ljubljani, Fak. za kemijo in kemijsko tehnologijo, UNI Kemija
Pages: 52 str.
ID: 19908973