diplomsko delo
Kristina Trogar (Author), Andrej Pevec (Mentor)

Abstract

Pripravila in analizirala sem nekatere halopiridinijeve heksafluoridotitanatne soli. Za sintezo spojin sem uporabljala titanov dioksid, ki je nastal s hidrolizo titanovega(IV) butoksida. Tako pripravljen TiO2 pa je reagiral z ustreznim halopiridinom: 2-fluoropiridin, 2-kloropiridin, 2-bromopiridin in 3-bromopiridin. Reakcije med TiO2 in halopiridini sem izvedla v različnih množinskih razmerjih. Nastale produkte sem analizirala z infrardečo spektroskopijo, nuklearno magnetno resonančno spektroskopijo, elementno analizo in rentgensko strukturno analizo.

Keywords

heksafluoridotitanat;halopiridin;sinteza;vodikova vez;kristalna struktura;karakterizacija;infrardeča spektroskopija;NMR spektroskopija;elementna analiza;rentgenska strukturna analiza;diplomske naloge;

Data

Language: Slovenian
Year of publishing:
Typology: 2.11 - Undergraduate Thesis
Organization: UL FKKT - Faculty of Chemistry and Chemical Technology
Publisher: [K. Trogar]
UDC: 546.824:547.82(043.2)
COBISS: 173434115 Link will open in a new window
Views: 92
Downloads: 3
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Other data

Secondary language: English
Secondary title: Sinthesis and Characterization of some Halopyridinium Hexafluoridotitanates
Secondary abstract: Some halopyridinium hexafluoridotitanate salts have been prepared and characterised. Titanium dioxide, which was used for the synthesis of the compounds, was prepared by hydrolysis of titanium(IV) butoxide. The TiO2 thus prepared then reacted with corresponding halopyridine: 2-fluoropyridine, 2-chloropyridine, 2-bromopyridine and 3-bromopyridine. Reactions between TiO2 and halopyridine were carried out in different molar ratio. The resulting products were analysed by infrared spectroscopy, nuclear magnetic resonance spectroscopy, elemental analysis and X-ray structural analysis.
Secondary keywords: hexafluoridotitanate;halopyridine;hydrogen bond;crystal structure;Soli;Univerzitetna in visokošolska dela;
Type (COBISS): Bachelor thesis/paper
Study programme: 1000374
Embargo end date (OpenAIRE): 1970-01-01
Thesis comment: Univ. v Ljubljani, Fak. za kemijo in kemijsko tehnologijo, VSŠ Kemijska tehnologija
Pages: 48 str.
ID: 20010371