diplomsko delo
Abstract
V diplomskem delu je predstavljena priprava rutenijevih koordinacijskih spojin piritionskih analogov s trifenilfosfinom/trifenilfosfitom ter njihova karakterizacija. Na piritionih je bila metilna skupina vezana na mestu 3, 4, 5 ali 6. Pri sintezi le-teh sem izhajala iz 2-kloropiridinov z metilno skupino na različnih mestih. Piritione sem vezala v komplekse z rutenijem. Na te komplekse sem v nadaljevanju vezala še trifenilfosfin ali trifenilfosfit. Pripravila sem deset kompleksov, od teh je osem novih. Te sem karakterizirala s pomočjo NMR, HRMS, CHN analize, IR in UV-Vis spektroskopije.
Keywords
ligandi;pirition;trifenilfosfin;trifenilfosfit;rutenijevi kompleksi;biološka aktivnost;diplomska dela;
Data
Language: |
Slovenian |
Year of publishing: |
2024 |
Typology: |
2.11 - Undergraduate Thesis |
Organization: |
UL FKKT - Faculty of Chemistry and Chemical Technology |
Publisher: |
[K. L. Lakota] |
UDC: |
546.96:547.82(043.2) |
COBISS: |
211928579
|
Views: |
132 |
Downloads: |
41 |
Average score: |
0 (0 votes) |
Metadata: |
|
Other data
Secondary language: |
English |
Secondary title: |
Synthesis of Ruthenium Complexes with Pyrithiones and Triphenylphosphine |
Secondary abstract: |
The aim of my work was the synthesis of ruthenium complexes with pyrithiones and triphenylphosphine/triphenylphosphite and their characterization. The methyl group was bound to the pyrithione analogues in positions 3, 4, 5 and 6. In the pyrithione synthesis, the product was obtained from 2-chloropyridines with the methyl group at various corresponding positions. The pyrithiones were bound in complexes with ruthenium and further with triphenylphosphine or triphenylphosphite. In the end, I obtained ten different new complexes, which were characterized by NMR, HRMS, CHN analysis, IR and UV-Vis spectroscopy |
Secondary keywords: |
pyrithione;triphenylphosphine;triphenylphosphite;ruthenium complexes;Koordinacijske spojine;Rutenij;Univerzitetna in visokošolska dela; |
Type (COBISS): |
Bachelor thesis/paper |
Study programme: |
1000373 |
Embargo end date (OpenAIRE): |
1970-01-01 |
Thesis comment: |
Univ. v Ljubljani, Fak. za kemijo in kemijsko tehnologijo, UNI Kemija |
Pages: |
1 spletni vir (1 datoteka PDF (93 str.)) |
ID: |
24920741 |