magistrsko delo
Žan Zakošek (Author), Amalija Golobič (Mentor), Matija Strlič (Thesis defence commission member), Anton Meden (Thesis defence commission member), Evgeny A. Goreshnik (Co-mentor)

Abstract

Opravil sem sistematično raziskavo ternarnega sistema CuBr - HBr - DABCO. Za pripravo novih spojin v izbranem ternarnem sistemu sem pripravil različna razmerja začetnih reaktantov (HBr, CuBr$_2$, DABCO) in izvedel elektrokemijsko (v acetonitrilu in etanolu) in solvotermalno (v acetonitrilu) sintezo izbranih razmerij. S pomočjo rentgenske difrakcije na monokristalih sem določil 7 novih kristalnih struktur v izbranem sistemu. Za vsako sintezo posebej sem izrisal graf ternarnega sistema CuBr - HBr - DABCO, v katerem sem označil pripravljena razmerja in faze, ki sem jih dobil v posamezni točki. Poleg željenih produktov sem hkrati določil še 7 novih kristalnih struktur stranskih produktov. Vse nove kristalne strukture predstavljene v tej magistrski nalogi sem naložil v CSD (Cambridge Structural Database).

Keywords

ternarni sistem;CuBr-HBr-DABCO;elektrokemijska sinteza;solvotermalna sinteza;rentgenska strukturna analiza na monokristalu;magistrska dela;

Data

Language: Slovenian
Year of publishing:
Typology: 2.09 - Master's Thesis
Organization: UL FKKT - Faculty of Chemistry and Chemical Technology
Publisher: [Ž. Zakošek]
UDC: 546.56:544.1(043.2)
COBISS: 207444227 Link will open in a new window
Views: 48
Downloads: 25
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Other data

Secondary language: English
Secondary title: Synthesis and structural characterization of compounds from the ternary system CuBr-HBr-bulky polyamine
Secondary abstract: I performed systematic investigation of ternary system CuBr - HBr - DABCO. For preparation of new compounds in the ternary system, I prepared different ratios of starting reactants (HBr, CuBr$_2$, DABCO) and performed electrochemical (in acetonitrile and ethanol) and solvothermal (in acetonitrile) synthesis. With single crystal X-ray diffraction, I determined 7 new crystal structures from the ternary system in question. For each synthesis procedure, I draw a graph of ternary system CuBr - HBr - DABCO in which, I marked prepared ratios and phases that were obtained in individual spots of the graph. I was also able to determine 7 new crystal structures of byproducts. All new crystal structures presented in this master thesis were deposited to CSD (Cambridge Structural Database).
Secondary keywords: CuBr-HBr-DABCO;single crystal X-ray diffraction;electrochemical synthesis;Anorganska sinteza (kemija);Univerzitetna in visokošolska dela;
Type (COBISS): Master's thesis/paper
Study programme: 1000375
Embargo end date (OpenAIRE): 1970-01-01
Thesis comment: Univ. v Ljubljani, Fak. za kemijo in kemijsko tehnologijo, smer Kemija
Pages: 1 spletni vir (1 datoteka PDF (69 str.))
ID: 24985043