Secondary abstract: |
When monitoring the quality of water, many different chemical and physical parameters must be taken into consideration. In this thesis, two nutrients: nitrogen and phosphorus (ammonia and phosphate ions, respectively), as representatives of inorganic water quality parameters, are discussed. With both analytes (NH3 and PO43-), we are confronted with the problem of their detection in aqueous media. In the case of ammonia (NH3), the available methods do not enable the determination of non-ionized ammonia (NH3), separately from the ammonium ion (NH4+), which is significantly less toxic than its gaseous form. In the case of PO43-, which is one of the eutrophication agents, the spectrometric method with ammonium molybdate is usually applied, but this also does not allow a direct and continuous detection of this analyte in water. In the proposed thesis, we present the development of new sensor receptors for optical detection and determination of the concentration of non-ionized ammonia (NH3) and phosphate ions (PO43-) in water. The indicators used are sensitive to ammonia and phosphates, and are colorimetric indicators (bromophenol blue – BPB, bromocresol green – BCG) or lanthanide complexes (europium-tetracycline complex and terbium complex), respectively. Both have been immobilized into a polymer support via the sol-gel process and applied to a glass carrier. Absorption and fluorescence (i.e. phosphorescence) are the optical methods, which were used for the determination of the mentioned analytes. The developed sensor receptors allow the determination of NH3 in the concentration range between 0,1 and 67,7 mg/L, and at a pH range defined under Slovenian legislation (pH 6,5-9). In the case of PO43- sensor receptors, we encountered some problems in sensing, therefore, apart from results, we present options and suggestions for further improvements in developing PO43- sensitive layers. |