diplomsko delo
Lea Dezire (Author), Barbara Modec (Mentor)

Abstract

Reakcije [Cu(kinal)2(CH3OH)]∙CH3OH (kinal⎼ je anion kinaldinske kisline, ki ima deprotonirano karboksilno skupino) s presežkom liganda s hidroksilno skupino vodijo do menjave labilnega metanola in koordinacije novega liganda. Tako sta bili pripravljeni dve novi koordinacijski spojini bakra(II): [Cu(kinal)2(4-hmpy)2], spojina s 4-hidroksimetilpiridinom (4-hmpy) in [Cu(kinal)2(Nmea)], spojina z N-metiletanolaminom (Nmea). Sestava spojin je bila razkrita z rentgensko strukturno analizo monokristalov.

Keywords

koordinacijske spojine;baker(II);kinaldinaska kislina;sinteza;

Data

Language: Slovenian
Year of publishing:
Typology: 2.11 - Undergraduate Thesis
Organization: UL FKKT - Faculty of Chemistry and Chemical Technology
Publisher: [L. Dezire]
UDC: 54(043.2)
COBISS: 11196489 Link will open in a new window
Views: 1613
Downloads: 310
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Other data

Secondary language: English
Secondary title: Characterization of the products of the copper(II) with quinaldinate reaction with ligands with hydroxyl group
Secondary abstract: Reactions of [Cu(kinal)2(CH3OH)]∙CH3OH (kinal⎼ stands for anion of quinaldic acid with a deprotonated carboxylic group) with an excess of a secondary ligand with a hydroxyl group have resulted in substitution of labile methanol and coordination of new ligand. Two novel coordination compounds of copper(II) were prepared: [Cu(kinal)2(4-hmpy)2], a complex with 4-hydroxymethylpyridine (4-hmpy), and [Cu(kinal)2(Nmea)], a complex with N-methylethanolamine (Nmea). Their compositions and structures were revealed by means of X-ray structure analysis on a single-crystal.
Secondary keywords: chemistry;kemija;
File type: application/pdf
Type (COBISS): Bachelor thesis/paper
Thesis comment: Univ. v Ljubljani, Pedagoška fak., Gospodinjstvo in kemija
Pages: 33 str.
ID: 9174927