diplomsko delo
Povzetek
Sintetizirala sem štiri bakrove(II) koordinacijske spojine z anionom 2-metilbenzojske kisline (= HL). To so Cu(L)2(H2O)2 1, Cu(L)(C2H3O2)(H2O) 2, Cu(L)2(C6H6N2O)2(H2O)2 3 in Cu2(L)4(C5H6N2)(H2O) 4. Kot topilo sem uporabila destilirano vodo. Bakrovim izhodnim spojinam sem dodajala 2-metilbenzojsko kislino, ki se na bakrov(II) ion veže kot anion. Poleg tega sem uporabljala tudi nevtralni ligand nikotinamid (C6H6N2O) in 2-aminopiridin (C5H6N2). Za vsako spojino sem pripravila tri enake sinteze, saj smo tako lahko sklepali, da je sinteza ponovljiva. Z rentgensko praškovno analizo smo primerjali difraktograme, iz katerih smo potrdili, da smo dobili iste koordinacijske spojine. S pomočjo CHN elementne analize smo ugotovili formule teh spojin.
Ključne besede
koordinacijske spojine;baker(II);bakrove spojine;ligandi;2-metilbenzojska kislina;nikotinamid;2-aminopiridin;diplomske naloge;
Podatki
Jezik: |
Slovenski jezik |
Leto izida: |
2020 |
Tipologija: |
2.11 - Diplomsko delo |
Organizacija: |
UL FKKT - Fakulteta za kemijo in kemijsko tehnologijo |
Založnik: |
[A. Hren] |
UDK: |
546.56:547.581.2(043.2) |
COBISS: |
39545603
|
Št. ogledov: |
464 |
Št. prenosov: |
107 |
Ocena: |
0 (0 glasov) |
Metapodatki: |
|
Ostali podatki
Sekundarni jezik: |
Angleški jezik |
Sekundarni naslov: |
Copper(II) compounds with 2-methylbenzoic acid anion |
Sekundarni povzetek: |
Four copper(II) coordination compounds with 2-methylbenzoic acid (= HL) anion have been synthesized. These are Cu(L)2(H2O)2 1, Cu(L)(C2H3O2)(H2O) 2, Cu(L)2(C6H6N2O)2(H2O)2 3 and Cu2(L)4(C5H6N2)(H2O) 4. Distilled water was used as a solvent. 2-Methylbenzoic acid, being added to the starting copper compounds, is bonded to the copper(II) ion as an anion. Neutral ligands nicotinamide (C6H6N2O) and 2 aminopyridine (C5H6N2) were added additionally. Each synthesis was proceeded tree times to deduce their reproducibility. The X-ray powder diffraction analysis was applied to confirm the identity of synthesized coordination compounds. Formulae of the synthesized compounds were determined with the CHN elemental analysis. |
Sekundarne ključne besede: |
copper(II);coordination compounds;2-methylbenzoic acid;nicotinamide;2-aminopyridine; |
Vrsta dela (COBISS): |
Diplomsko delo/naloga |
Študijski program: |
1000374 |
Konec prepovedi (OpenAIRE): |
1970-01-01 |
Komentar na gradivo: |
Univ. v Ljubljani, Fak. za kemijo in kemijsko tehnologijo, VSŠ Kemijska tehnologija |
Strani: |
30 str |
ID: |
12103889 |