Anže Zupanc (Avtor), Marjan Jereb (Avtor)

Povzetek

This is the first report on the synthesis and characterization of N-iodo sulfoximines. The synthesis was designed as a room temperature one-pot cascade reaction from readily available sulfides as starting compounds, converted into sulfoximines by reaction with ammonium carbonate and (diacetoxyiodo)benzene, followed by iodination with N-iodosuccinimide or iodine in situ, in up to 90% isolated yields, also at a multigram scale. Iodination of aryls with N-iodo sulfoximines, oxidation, and conversion to N-SCF$_3$ congeners have been demonstrated.

Ključne besede

sulfidi;sulfoksimini;enolončna pretvorba;N-jodo sulfoksimini;sulfides;sulfoximines;one-pot;N-iodo sulfoximines;

Podatki

Jezik: Angleški jezik
Leto izida:
Tipologija: 1.01 - Izvirni znanstveni članek
Organizacija: UL FKKT - Fakulteta za kemijo in kemijsko tehnologijo
UDK: 547.544
COBISS: 58059779 Povezava se bo odprla v novem oknu
ISSN: 0022-3263
Št. ogledov: 357
Št. prenosov: 195
Ocena: 0 (0 glasov)
Metapodatki: JSON JSON-RDF JSON-LD TURTLE N-TRIPLES XML RDFA MICRODATA DC-XML DC-RDF RDF

Ostali podatki

Sekundarni jezik: Slovenski jezik
Sekundarne ključne besede: sulfidi;sulfoksimini;enolončna pretvorba;N-jodo sulfoksimini;
Vrsta dela (COBISS): Članek v reviji
Komentar vira: This is the first report on the synthesis and characterization of N-iodo sulfoximines. The synthesis was designed as a room temperature one-pot cascade reaction from readily available sulfides as starting compounds, converted into sulfoximines by reaction with ammonium carbonate and (diacetoxyiodo)benzene, followed by iodination with N-iodosuccinimide or iodine in situ, in up to 90% isolated yields, also at a multigram scale. Iodination of aryls with N-iodo sulfoximines, oxidation, and conversion to N-SCF3 congeners have been demonstrated.
Strani: str. 5991-6000
Letnik: ǂVol. ǂ86
Zvezek: ǂiss. ǂ8
Čas izdaje: 16 Apr. 2021
DOI: 10.1021/acs.joc.1c00292
ID: 12963092