diplomsko delo
Nika Kunavar (Avtor), Marjan Jereb (Mentor)

Povzetek

Izraz diazo se nanaša na prisotnost dveh dušikovih atomov, pritrjenih na konec organske spojine. Diazo spojine poznamo v kemiji kot vsestranske substrate za številne kemične prevorbe, katere v diplomskem delu tudi opišem. Dve najbolj poznani sintezi diazo spojin sta diazotiranje in Arndt-Eistertova sinteza. Primer preproste diazo spojine je diazometan, ki je znan po svoji rumeni barvi ter eksplozivnosti, zato z njim ravnamo posebej previdno. V diplomi se posvečam sami sintezi in pretvorbam diazometana, ki so trenutno najbolj prepoznavne. Pomembni intermediati v organski kemiji so diazonijeve soli, predvsem aromatske diazonijeve soli. V industriji barvil je pomembna uporaba stabiliziranih diazonijevih soli v obliki kompleksov z nekaterimi solmi ali z dodatki raznih anorganskih soli oziroma v obliki diazotatov. Pretvorbe diazonijevih soli sem razdelila v dve skupini: brez odcepa in z odcepom dušikove molekule. Med tiste, kjer se dušik odcepi, spadata Sandmeyerjeva in Gattermannova reakcija. Med tiste, kjer pa se cepitev ne zgodi, pa reakcije pripajanja. Opišem tudi samo nestabilnost diazonijevih soli ter potencialne vzroke zanjo. Diazo spojino predstavim kot nukleofil, ki lahko reagira z Lewisovo kislino. Opišem tudi pretvorbo azida ter hidrazona v diazonijevo spojino ter se posvetim kataliziranim pretvorbam diazo spojin v prisotnosti železa ali zlata.

Ključne besede

diazometan;diazonijeve soli;pretvorbe diazonijevih spojin;sinteza;katalizirane pretvorbe;diplomska dela;

Podatki

Jezik: Slovenski jezik
Leto izida:
Tipologija: 2.11 - Diplomsko delo
Organizacija: UL FKKT - Fakulteta za kemijo in kemijsko tehnologijo
Založnik: [N. Kunavar]
UDK: 54-304.4(043.2)
COBISS: 120723715 Povezava se bo odprla v novem oknu
Št. ogledov: 39
Št. prenosov: 14
Ocena: 0 (0 glasov)
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Ostali podatki

Sekundarni jezik: Angleški jezik
Sekundarni naslov: Synthesis and some conversions of diazo compounds
Sekundarni povzetek: The term diazo refers to the presence of two nitrogen atoms attached to the final end of an organic compound. Diazo compounds are known in chemistry as versatile substrates for chemical transformations, which I also describe in my thesis. The two best known syntheses of diazo compounds are diazotization and Arndt-Eistert synthesis. An example of a simple diazo compound is diazomethane, which is known for its yellow colour and explosiveness, and should therefore be handled with special care. In my thesis I focus on the synthesis and conversions of diazomethane, which are currently the most known Diazonium salts, especially aromatic diazonium salts, are important intermediates in organic chemistry. In the dye industry, the use of stabilized diazonium salts in the form of complexes with certain salts or with the addition of various inorganic salts, or in the form of diazotates, is very important. I have divided the diazonium salt conversions into two groups: substitutions where nitrogen atoms remain in the product and substitutions where N2 eliminates. The Sandmeyer and the Gattermann reactions are among those where nitrogen eliminates. Among those where cleavage does not occur are the coupling reactions. I also describe the instability of diazonium salts and the potential causes for it. I present the diazo compound as a nucleophile that can react with the Lewis acid. I also describe the conversion of azide and hydrazone to diazonium compound and discuss the catalyzed conversions of diazo compounds in the presence of iron or gold.
Sekundarne ključne besede: diazo compounds;diazomethane;diazonium salts;conversions of diazonium compounds;synthesis;Diazospojine;Univerzitetna in visokošolska dela;
Vrsta dela (COBISS): Diplomsko delo/naloga
Študijski program: 1000373
Konec prepovedi (OpenAIRE): 1970-01-01
Komentar na gradivo: Univ. v Ljubljani, Fak. za kemijo in kemijsko tehnologijo, UNI Kemija
Strani: 24 str.
ID: 16270679