Amadeja Koler (Avtor), Peter Krajnc (Avtor)

Povzetek

Porous polymer networks were synthesized via thiol-ene photo-polymerization using a naturally occurring terpene, myrcene and the multifunctional thiol, trimethylolpropane tris(3-mercaptopropionate). A highly porous structure (up to 80% porosity) was achieved by polymerizing the monomeric phase of high internal phase emulsions (HIPEs), composed of myrcene and trimethylolpropane tris(3-mercaptopropionate) in the presence of ethylene glycol dimethacrylate, which facilitated the formation of polyHIPE materials. Myrcene was incorporated in concentrations ranging from 9 to 40 mol%, and its content was found to significantly influence the resulting polymer morphology. Depending on the formulation, both bicontinuous-like and open-cell polyHIPE morphologies were obtained. In addition to myrcene content, the thiol-to-alkene functional group ratio (1:1 ratio of thiol to alkene groups, as well as formulations with an excess of alkene functionalities relative to thiols).

Ključne besede

fotokemija;terpeni;mircen;polimeri;photochemistry;terpenes;thiol-ene reaction;polyHIPEs;myrcene;

Podatki

Jezik: Angleški jezik
Leto izida:
Tipologija: 1.01 - Izvirni znanstveni članek
Organizacija: UM FKKT - Fakulteta za kemijo in kemijsko tehnologijo
Založnik: Springer
UDK: 66
COBISS: 245079299 Povezava se bo odprla v novem oknu
ISSN: 1434-4475
Št. ogledov: 0
Št. prenosov: 2
Ocena: 0 (0 glasov)
Metapodatki: JSON JSON-RDF JSON-LD TURTLE N-TRIPLES XML RDFA MICRODATA DC-XML DC-RDF RDF

Ostali podatki

Sekundarni jezik: Slovenski jezik
Sekundarne ključne besede: fotokemija;terpeni;mircen;polimeri;
Vrsta dela (COBISS): Članek v reviji
Strani: 7 str.
Čas izdaje: Published: 04 August 2025
DOI: 10.1007/s00706-025-03360-2
ID: 27012770
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