Multi-scale modelling of Lithium-ion batteries

from transport phenomena to the outbreak of thermal runaway

Tomaž Katrašnik (Author), Igor Mele (Author), Klemen Zelič (Author)

Abstract

Multi-scale and multi-domain mathematical models capable of modelling main electrochemical reactions, side reactions and heat generation can reduce the time and cost of lithium-ion battery development and deployment, since these processes decisively influence performance, durability and safety of batteries. Experimental evidences clearly indicate the importance of the interplay between electric and thermal boundary conditions, cell design and applied materials, side reactions as well as safety implications of batteries, which are not yet captured to a sufficient level by simulations models. As an answer to this challenge, the paper presents an advanced multi-scale battery modelling framework that can be seamlessly integrated into multi-domain models. The key hypothesis is that nanoscopic transport phenomena and resulting heat generation decisively influence the entire chain of mechanisms that can lead to the outbreak of the thermal runaway. This is confirmed by developing a multi-scale battery modelling framework that is based on the continuous modelling approach featuring more consistent virtual representation of the electrode topology and incorporating the coupled chain of models for heat generations and side reactions. As a result, the battery modelling framework intuitively yet insightfully elucidates the entire chain of phenomena from electric and thermal boundary conditions, over cell design and properties of applied materials to solid electrolyte interphase growth, its decomposition and subsequent side reactions at the anode, cathode and the electrolyte that lead to the thermal runaway. One of key results comprises multi-level main and side reaction driven heat transfer cross-talk between the anode and the cathode. Therefore, the presented advanced multi-scale battery modelling framework represents a contribution to the advanced virtual development of batteries thereby contributing to tailoring battery design to a specific application.

Keywords

Li-ion battery;phase separating material;continuum model;multi-scale modelling;heat generation;thermal runaway;

Data

Language:	English
Year of publishing:	2021
Typology:	1.01 - Original Scientific Article
Organization:	UL FS - Faculty of Mechanical Engineering
UDC:	621.31:519.8(045)
COBISS:	58992387
ISSN:	0196-8904
Views:	359
Downloads:	139
Average score:	0 (0 votes)
Metadata:

Other data

Secondary language:	Slovenian
Secondary keywords:	Li-ionska baterije;material s fazno separacijo;kontinuumski model;več-skalno modeliranje;generacija toplote;termični pobeg;
Type (COBISS):	Article
Pages:	str. 1-22
Issue:	ǂVol. ǂ236
Chronology:	May 2021
DOI:	10.1016/j.enconman.2021.114036
ID:	12795274