magistrsko delo
Katarina Barbara Reberc (Author), Krištof Kranjc (Mentor), Miha Lukšič (Thesis defence commission member), Uroš Grošelj (Thesis defence commission member)

Abstract

V magistrskem delu so predstavljeni 2H-piran-2-oni, različne sintezne poti in njihova reaktivnost v različnih reakcijah. Ena izmed možnih pretvorb je preko cikloadicijskih reakcij, ki vodijo do zanimivih biciklo[2.2.2]oktenskih sistemov. V eksperimentalnem delu sem se posvetila reakcijam 2H-piran-2-onov z maleinanhidridom, pri katerih so glavni produkti različno substituirani biciklo[2.2.2]okteni, v nekaterih primerih pa je možen tudi nastanek aromatskih derivatov izobenzofurana. Analiza rezultatov omogoča vpogled v vplive na reaktivnost 2H-piran-2-onov v Diels–Alderjevih reakcijah.

Keywords

heterociklična kemija;2H-piran-2-oni;biciklo[2.2.2]okteni;Diels-Alderjeva reakcija;magistrska dela;

Data

Language: Slovenian
Year of publishing:
Typology: 2.09 - Master's Thesis
Organization: UL FKKT - Faculty of Chemistry and Chemical Technology
Publisher: [K. B. Reberc]
UDC: 547.81(043.2)
COBISS: 173236227 Link will open in a new window
Views: 87
Downloads: 17
Average score: 0 (0 votes)
Metadata: JSON JSON-RDF JSON-LD TURTLE N-TRIPLES XML RDFA MICRODATA DC-XML DC-RDF RDF

Other data

Secondary language: English
Secondary title: Synthesis and derivatization of novel 3-benzoylamino-2H-pyran-2-ones to bicyclo[2.2.2]octene compounds
Secondary abstract: The master's thesis presents 2H-pyran-2-ones, different synthetic routes and their reactivity in various reactions. One of the possible transformations is via cycloaddition reactions leading to interesting bicyclo[2.2.2]octene systems. In the experimental work, I focused on the reactions of 2H-pyran-2-ones with maleic anhydride, in which the main products are variously substituted bicyclo[2.2.2]octenes, with possible formation of aromatic derivatives of isobenzofuran in some cases. Analysis of the results provides insight into the effects on the reactivity of 2H-pyran-2-ones in Diels–Alder reactions.
Secondary keywords: 2H-pyran-2-ones;bicyclo[2.2.2]octenes;heterocyclic chemistry;Diels-Alder reaction;Pirani;Organska sinteza (kemija);Univerzitetna in visokošolska dela;
Type (COBISS): Master's thesis/paper
Study programme: 1000375
Embargo end date (OpenAIRE): 1970-01-01
Thesis comment: Univ. v Ljubljani, Fak. za kemijo in kemijsko tehnologijo, smer Kemija
Pages: 66 str.
ID: 19999899