magistrsko delo
Matej Jarc Rydzi (Author), Jurij Svete (Mentor), Matija Strlič (Thesis defence commission member), Bogdan Štefane (Thesis defence commission member)

Abstract

Enaminoketoni so pomembna skupina organskih spojin, ki nastopajo v mnogih reakcijah organske sinteze, kot je na primer sinteza heterocikličnih spojin. Iz enaminoketonov lahko pripravimo β-ketoiminatne komplekse. Ti kompleksi imajo zanimive optične lastnosti, kar nakazuje tudi na njihovo možno uporabnost v fotokemijskih transformacijah, ki so zaenkrat slabo raziskane. Zato sem poskusil razviti nove fotokemijske pretvorbe teh spojin. Ker so bile te reakcije le delno uspešne, sem se osredotočil na izhodne enaminoketone kot substrate za fotokemijske pretvorbe. Na tem področju sem bil bolj uspešen in sem naredil začetne poskuse za razvoj novih fotokemijskih transformacij na teh spojinah. Hkrati sem enaminoketone reagiral s klorosulfonil izocianatom, da sem pridobil substrate za fotoredoks reakcije.

Keywords

enaminoketoni;▫$\beta$▫-ketoiminatni kompleksi;fotoredoks pretvorbe;radikalska adicija s prenosom atoma;ATRA reakcija;magistrska dela;

Data

Language: Slovenian
Year of publishing:
Typology: 2.09 - Master's Thesis
Organization: UL FKKT - Faculty of Chemistry and Chemical Technology
Publisher: [M. Jarc Rydzi]
UDC: 547:544.526(043.2)
COBISS: 195796483 Link will open in a new window
Views: 61
Downloads: 10
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Other data

Secondary language: English
Secondary title: Synthesis of selected enaminoketones and their use in different photochemical transformations
Secondary abstract: Enaminoketones are an important class of organic compounds with versatile applicability in organic synthesis, in particular in the synthesis of heterocyclic compounds. β-Ketoiminate complexes can be derived from the aforementioned compounds. These complexes have interesting optical properties, which suggest their possible use as substrates in photochemical transformations, which remain under-examined. This led to the attempt to develop new photochemical transformations of these compounds. Unfortunately, despite efforts, this achievement was elusive, thus I decided to focus on the starting enaminoketones as potential substrates for photochemical transformations. The efforts were successful, and the groundwork was laid for the development of novel photochemical reactions of these compounds. In parallel with the main topic, the aforementioned compound was reacted with chlorosulfonyl isocyanate, thus producing potential substrates for photoredox reactions.
Secondary keywords: enaminoketones;▫$\beta$▫-ketoiminate complexes;photochemistry;photoredox conversions;Fotokemija;Ketoni;Univerzitetna in visokošolska dela;
Type (COBISS): Master's thesis/paper
Study programme: 1000375
Embargo end date (OpenAIRE): 1970-01-01
Thesis comment: Univ. v Ljubljani, Fak. za kemijo in kemijsko tehnologijo, smer Kemija
Pages: 1 spletni vir (1 datoteka PDF (76 str.))
ID: 23636639