Janez Stepišnik (Author), Aleš Mohorič (Author)

Abstract

A more detailed insight into the chemical kinetics and dynamics of chemical exchanges within a molecule or between molecules in liquids is made possible by the NMR CPMG method, which, in addition to the exchange rate, gives its power spectrum, which contains information about the underlying processes of chemical exchange. The applicability of the method is demonstrated by measuring the chemical exchange in an aqueous solutions of sucrose, whose rate spectra have shapes that cannot be explained as transitions in a double potential well, but after interpretation using the chemical Langevin equations, it can be explained as a cascading chemical transition across several intermediate potential walls.

Keywords

jedrska magnetna resonanca;nuclear magnetic resonance;

Data

Language: English
Year of publishing:
Typology: 1.01 - Original Scientific Article
Organization: UL FMF - Faculty of Mathematics and Physics
UDC: 537.635
COBISS: 202786051 Link will open in a new window
ISSN: 0937-9347
Views: 23
Downloads: 4
Average score: 0 (0 votes)
Metadata: JSON JSON-RDF JSON-LD TURTLE N-TRIPLES XML RDFA MICRODATA DC-XML DC-RDF RDF

Other data

Secondary language: Slovenian
Secondary keywords: jedrska magnetna resonanca;
Type (COBISS): Article
Pages: 8 str.
Chronology: 2024
DOI: 10.1007/s00723-024-01679-3
ID: 24817769