Janez Stepišnik (Avtor), Aleš Mohorič (Avtor)

Povzetek

A more detailed insight into the chemical kinetics and dynamics of chemical exchanges within a molecule or between molecules in liquids is made possible by the NMR CPMG method, which, in addition to the exchange rate, gives its power spectrum, which contains information about the underlying processes of chemical exchange. The applicability of the method is demonstrated by measuring the chemical exchange in an aqueous solutions of sucrose, whose rate spectra have shapes that cannot be explained as transitions in a double potential well, but after interpretation using the chemical Langevin equations, it can be explained as a cascading chemical transition across several intermediate potential walls.

Ključne besede

jedrska magnetna resonanca;nuclear magnetic resonance;

Podatki

Jezik: Angleški jezik
Leto izida:
Tipologija: 1.01 - Izvirni znanstveni članek
Organizacija: UL FMF - Fakulteta za matematiko in fiziko
UDK: 537.635
COBISS: 202786051 Povezava se bo odprla v novem oknu
ISSN: 0937-9347
Št. ogledov: 23
Št. prenosov: 4
Ocena: 0 (0 glasov)
Metapodatki: JSON JSON-RDF JSON-LD TURTLE N-TRIPLES XML RDFA MICRODATA DC-XML DC-RDF RDF

Ostali podatki

Sekundarni jezik: Slovenski jezik
Sekundarne ključne besede: jedrska magnetna resonanca;
Vrsta dela (COBISS): Članek v reviji
Strani: 8 str.
Čas izdaje: 2024
DOI: 10.1007/s00723-024-01679-3
ID: 24817769