doktorska disertacija
Povzetek
Osnovno izhodišče dela je definirati tak cementni kompozit z dodatkom bele (ponovčne) žlindre, ki bo
zagotavljal funkcionalnost za izbrane namene ter hkrati preprečeval širjenje škodljivih snovi v okolje.
Ponovna uporaba (recikliranje) sekundarnih metalurških žlinder iz proizvodnje nerjavnega jekla ima
namreč pomemben sinergijski učinek na okolje. V okviru preiskav smo se osredotočili na podrobno
karakterizacijo žlindre, ki izhaja iz dveh različnih procesov sekundarne rafinacije visoko legiranega
jekla v ponovci ter na cementne kompozite z dodatkom le-te. V sklopu laboratorijskih raziskav je bilo
preiskanih več cementnih kompozitov z dodatkom bele ponovčne žlindre. Vzporedno so bili za
primerjavo preiskani tudi referenčni cementni kompoziti in kompoziti z dodatkom konvencionalnega
suplementarnega cementnega materiala (apnenčeva moka). Rezultati kažejo, da dobrih 50 mas. %
preiskovane žlindre sestavljajo hidravlično aktivni minerali, med katerimi močno prevladujejo
kalcijevi aluminati. Malte z dodatkom preiskovane žlindre izkazujejo večjo stopnjo prirastka trdnosti v
primerjavi z maltami z dodatkom apnenčeve moke, kar je posledica večje količine nastalih
hidratacijskih produktov. Dodajanje preiskovane žlindre cementnim kompozitom je bilo ocenjeno tudi
iz vidika okoljskih vplivov na podlagi dolgoročnega izlužitvenega testa. Preiskovana žlindra stabilizira
krom z njenimi redukcijskimi in hidravličnimi karakteristikami, kar kaže na pomemben pozitiven
učinek preiskovane žlindre v cementnem kompozitu. V okviru mehanskih preiskav malt po
izlužitvenem testu je bila ovrednotena trajnost, ki kaže na to, da preiskovana žlindra ne zmanjšuje
trajnosti tovrstnih malt. Rezultati kažejo, da se preiskovana bela ponovčna žlindra lahko uporabi kot
suplementarni cementni material.
Ključne besede
Grajeno okolje;geologija;disertacije;bela žlindra;imobilizacija;cementni kompoziti;hidratacija;krom;
Podatki
Jezik: |
Slovenski jezik |
Leto izida: |
2015 |
Tipologija: |
2.08 - Doktorska disertacija |
Organizacija: |
UL FGG - Fakulteta za gradbeništvo in geodezijo |
Založnik: |
[V. Zalar Serjun] |
UDK: |
625.821.4:669(497.4)(043.3) |
COBISS: |
7105889
|
Št. ogledov: |
1713 |
Št. prenosov: |
519 |
Ocena: |
0 (0 glasov) |
Metapodatki: |
|
Ostali podatki
Sekundarni jezik: |
Angleški jezik |
Sekundarni naslov: |
Characterization and immobilization of white slag from secondary metallurgical processes in cementitious composites |
Sekundarni povzetek: |
The fundamental objective of this study was to define such a cement composite with the addition of
white (ladle) slag, which will provide functionality for selected purposes and furthermore, prevent the
leaching of toxic elements into the environment. The recovery (recycling) of secondary metallurgical
slags from stainless steel production has an important synergistic impact on the environment. In this
study, detailed characterization of slag derived from two different ladle refining processes of stainless
steel production has been performed. In order to assess its potential for use as a supplementary
cementitious material, slag cement composites as well as slag itself were investigated. A comparative
study of reference cement composites and cement composites to which a conventional supplementary
cementitious material (limestone filler) had been added, was also performed. The results showed that
the slag contains hydraulic phases to a total amount of about 50 %. Calcium aluminates are the
predominant constituents. In the case of slag cement composites, a larger degree of strength
development was observed in comparison to the cement composite with the addition of limestone
filler. This was attributed to the larger proportion of hydration products formed in the slag cement
composite. The environmental impact of cement composite with the addition of the investigated slag
was further evaluated. The results revealed that chromium was immobilized in the cement composites
with the addition of slag. Cr(VI) content originating from the cement was also appreciably reduced by
the added slag, which thus had significant positive environmental effects. The stabilization process is
controlled by the reducing and hydraulic properties of the slag. It was demonstrated that the presence
of the investigated slag in cement composites does not influence its durability. The investigated white
(ladle) slag can be implemented in cement composites as supplementary cementitious material. |
Sekundarne ključne besede: |
Built Environment;geology;doctoral thesis;ladle slag;immobilization;cement composites;hydration;chromium; |
Vrsta datoteke: |
application/pdf |
Vrsta dela (COBISS): |
Doktorsko delo/naloga |
Komentar na gradivo: |
Univ. v Ljubljani, Naravoslovnotehniška fak. |
Strani: |
XXVIII, 169 str. |
ID: |
8773694 |