Alenka Ojstršek (Avtor), Aleš Doliška (Avtor), Darinka Fakin (Avtor)

Povzetek

The objective of the presented research was to examine the potential of capillary electrophoresis (CE) for the analysis of structurally different reactive dyestuffs, their activation and posterior hydrolysis, with special focus on optimization of the working conditions. Preliminary, the effect of various additives to the background electrolyte on the resolution improvements versus migration time of Reactive Black 5 as a model dyestuff was investigated. Based on these results, the electropherograms of eight commercially interesting reactive dyestuffs of various chemical structures and their converted forms upon alkaline pH were carried-out. In order to examine the behavior of the reactive dyestuff during the dyeing process, the dye-bath absorbance was monitored throughout the Reactive Black 5 exhaustion, and the conversion of the dye's form was highlighted using the CE technique. The obtained results unequivocally prove that CE could offer a fast and efficient detection method of structurally different reactive dyestuffs, as well as their hydrolysis products in the dye-baths and effluents later on.

Ključne besede

capillary electrophoresis;dyes;hydrolysis;

Podatki

Jezik: Angleški jezik
Leto izida:
Tipologija: 1.01 - Izvirni znanstveni članek
Organizacija: UM FS - Fakulteta za strojništvo
UDK: 543.54:667
COBISS: 12872214 Povezava se bo odprla v novem oknu
ISSN: 0910-6340
Št. ogledov: 1573
Št. prenosov: 64
Ocena: 0 (0 glasov)
Metapodatki: JSON JSON-RDF JSON-LD TURTLE N-TRIPLES XML RDFA MICRODATA DC-XML DC-RDF RDF

Ostali podatki

Sekundarni jezik: Angleški jezik
URN: URN:SI:UM:
Strani: str. 1581-1587
Letnik: ǂVol. ǂ24
Zvezek: ǂno ǂ12
Čas izdaje: Dec. 2008
Ključne besede (UDK): mathematics;natural sciences;naravoslovne vede;matematika;chemistry;crystallography;mineralogy;kemija;analytical chemistry;analizna kemija;physicochemical methods of analysis (other than optical methods);applied sciences;medicine;technology;uporabne znanosti;medicina;tehnika;chemical technology;chemical and related industries;kemijska tehnologija;kemijske in sorodne industrije;colour industries;industrija barvil;
ID: 990568