diplomsko delo univerzitetnega študijskega programa
Povzetek
IZBIRA MATERIALA ZA KONTROLO KAKOVOSTI POTENCIALA ZETA TRDNIH POVRŠIN
Povzetek
Zanesljive rezultate meritev lahko zagotovimo le z brezhibnim delovanjem merilnih naprav, katerih zmogljivost pa se s časom in uporabo slabša. Pravilno delovanje merilne naprave lahko preverimo z referenčnim materialom. Tudi elektrokinetični analizator SurPASS, ki je na tržišču relativno kratek čas, je podvržen različnim vplivom in potrebuje material za kontrolo kakovosti potenciala zeta. Instrument SurPASS namreč omogoča merjenje pretočnega toka, s katerim določimo t.i. potencial zeta, ki določa stanje površinskega naboja na mejni površini trdnega telesa in tekočine. Izbire trdnega materiala z ravno površino, ki je primeren za merjenje v merilni celici CLC, smo se lotili z meritvami časovne odvisnosti potenciala zeta na polimerih (PTFE, PES in PET) ter steklu. Najbolj stabilne meritve dajeta vzorca PES in PET, ki sta glede na dobljene rezultate konstante hitrosti nabrekanja tudi najbolj hidrofobna. Zato smo meritve nadaljevali na teh dveh materialih. Statistična analiza rezultatov teh meritev nakazuje na homogenost obeh materialov, čeprav v nekaterih primerih daje prednost materialu PES, spet drugič PET. Takšne nasprotujoče si rezultate meritev lahko pripišemo tudi napakam v meritvah (omočenost nemerjene površine vzorca v CLC) in ne nujno nehomogenosti materiala.
Ključne besede
referenčni materiali;polimerni materiali;elektrokinetične lastnosti;pretočni tok;potencial zeta;
Podatki
Jezik: |
Slovenski jezik |
Leto izida: |
2010 |
Izvor: |
Maribor |
Tipologija: |
2.11 - Diplomsko delo |
Organizacija: |
UM FKKT - Fakulteta za kemijo in kemijsko tehnologijo |
Založnik: |
[M. Rudaš] |
UDK: |
678.7:544.638(043.2) |
COBISS: |
15001878
|
Št. ogledov: |
2368 |
Št. prenosov: |
140 |
Ocena: |
0 (0 glasov) |
Metapodatki: |
|
Ostali podatki
Sekundarni jezik: |
Angleški jezik |
Sekundarni naslov: |
Materials selection for the zeta potential quality-control of solid surfaces |
Sekundarni povzetek: |
MATERIALS SELECTION FOR THE ZETA POTENTIAL QUALITY-CONTROL OF SOLID SURFACES
Abstract
Reliable results of measurements can only be assured by using faultless measuring instruments, the efficiencies of which do, regrettably, deteriorate over time and usage. The correct functioning of instruments can be examined using reference materials. The SurPASS electrokinetic analyser, which has only been on the market for a relatively short time, is also subject to different influences and therefore needs a material for zeta potential quality control. The SurPASS instrument enables the measurement of streaming-current which helps us to determine the so-called zeta potential, which then indicates the status of the surface-charge on the border area of a solid or liquid. We began by selecting a solid material with a flat surface, which would be suitable for the CLC measuring cell, using the measurements of time-dependence regarding zeta potential on polymers (PTFE, PES and PET), and glass. The more stable measurements were given for samples PES and PET, for which it provided the more constant results, and also the most hydrophobic materials. Consequently, we continued our measurements on the afore-mentioned two materials. Statistical analysis of these results indicated the homogeneities of both materials although, in some cases, it gave an advantage to PES, and then the second time to PET. These kinds of contradictive measurement results can also be annotated to mistakes during the measuring process (wettability of the non-measured surface sample in CLC), and not necessarily to any non-homogeneity of the material. |
Sekundarne ključne besede: |
reference material;polymeric materials;electrokinetic properties;streaming current;zeta potential; |
URN: |
URN:SI:UM: |
Vrsta dela (COBISS): |
Diplomsko delo |
Komentar na gradivo: |
Univ. v Mariboru, Fak. za kemijo in kemijsko tehnologijo |
Strani: |
XII, 78 f. |
Ključne besede (UDK): |
applied sciences;medicine;technology;uporabne znanosti;medicina;tehnika;various industries;trades and crafts;razne industrije;obrti in rokodelstva;industries based on macromolecular materials;rubber industry;plastics industry;industrija makromolekulskih snovi;industrija kavčuka;industrija umetnih snovi;synthetic polymerization products;polymerizates;synthetic rubbers;sintetični polimerizacijski produkti;polimerizati;sintetični kavčuk;mathematics;natural sciences;naravoslovne vede;matematika;chemistry;crystallography;mineralogy;kemija;physical chemistry;fizikalna kemija;electrochemistry; |
ID: |
996177 |