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Oznake: antiferomagnetizem;magneto-kalorični efekt;antiferromagnetism;magnetocaloric effect;Gd-silsesquioxane;crystal structure;archimedean solid;magnetic property;
Polynuclear metal clusters, particularly those with aesthetically appealing structures, are of increasing interest. In this study, by employing C4 symmetrical macrocyclic silsesquioxane ligand, a novel tridecanuclear Gd(III) cluster (Gd13) with a {Gd13O8} core featuring unprecedent body-centered Arc ...
Leto: 2022 Vir: Fakulteta za gradbeništvo in geodezijo (UL FGG)
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Oznake: Mn(III)-Mn(IV) spojina;antiferomagnetizem;Mn(III)-Mn(IV) compound;antiferromagnetism;
The mild reaction of the preorganized silsesquioxane precursor with Mn(II) acetate under ambient conditions results in a mixed-valent {MnII 6MnIII4} nanocage (SD/Mn10) which is protected by both acyclic trimer [Si3] and cyclic tetramer [Si4]. Serendipitous capture of atmospheric CO2 as a μ5-carbonat ...
Leto: 2021 Vir: Fakulteta za gradbeništvo in geodezijo (UL FGG)
Št. zadetkov: 2
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