occurrence, pattern and correlations
Povzetek
This four-year study reports the occurrence of ergot alkaloids (EAs) in cereals intended for animal feeding collected in Slovenia. A total of 517 samples of cereals were analysed using liquid chromatography-tandem mass spectrometry for the presence of EAs. The sample set included wheat, rye, triticale, oat, spelt and barley. The study revealed that 17% of the analysed cereal samples were contaminated with at least one ergot alkaloid. EAs have two epimeric forms: -ine and -inine. The incidence rates of the -ine and -inine forms in the analysed samples were 16% and 15%, respectively. The highest contamination rates were observed in rye (54%), oat (50%) and spelt (30%), where the highest mean concentrations of total EAs were also determined (502 µg/kg, 594 µg/kg and 715 µg/kg, respectively). However, the highest concentrations of total EAs were found in wheat and rye (4217 µg/kg and 4114 µg/kg, respectively). The predominant EAs were ergometrine, ergosine and ergocristinine. The occurrence of six or more ergot alkaloids was observed in 49% of the positive samples. A weak correlation (p = 0.284) in the positive samples was found between the mass of sclerotia and the total concentrations of EAs using the Spearman correlation coefficient.
Ključne besede
animal feed;analysis;toxicity;ergot alkaloid occurrence;cereals;LC-MS/MS;correlation;survey;sclerotia;alkaloids;edible grain;questionnaires;
Podatki
Jezik: |
Angleški jezik |
Leto izida: |
2020 |
Tipologija: |
1.01 - Izvirni znanstveni članek |
Organizacija: |
UL VF - Veterinarska fakulteta |
UDK: |
636.082:615.9:543:547 |
COBISS: |
40459011
|
ISSN: |
2072-6651 |
Št. ogledov: |
377 |
Št. prenosov: |
125 |
Ocena: |
0 (0 glasov) |
Metapodatki: |
|
Ostali podatki
Sekundarne ključne besede: |
Animal feed;Analysis;Toxicity;Alkaloids;Edible Grain;Surveys and Questionnaires; |
Vrsta dela (COBISS): |
Članek v reviji |
Strani: |
art. 730, str. 1-18, S1-S2 |
Letnik: |
ǂVol. ǂ12 |
Zvezek: |
ǂiss. ǂ11 |
Čas izdaje: |
2020 |
DOI: |
10.3390/toxins12110730 |
ID: |
12216171 |