preparation and void size tuning

Povzetek

Preparation of highly porous (up to 80% pore volume) open-cellular monolithic cross-linked polymers from 2-hydroxyethyl methacrylate is reported. Oil-in-water and water-in-oil high internal phase emulsions are applied as porosity templates, resulting in an interconnected porous structure with void diameters between 550 nm and 18 m. Significantly larger voids were obtained inthe case of oil-in-water emulsions (between 5 and 18 m) as opposed to water in oil emulsions (approx 600 nm). Controlled coarsening exploiting limited kinetical stability of emulsions was used to obtain monoliths with larger voids, diameters being enlarged 3-fold.

Ključne besede

organska kemija;polimerizacija;monolitni polimeri;HIPE;emulzije;porozni materiali;metakrilati;organic chemistry;polymerization;monolithic polymers;emulsions;porous materials;methacrylates;

Podatki

Jezik: Angleški jezik
Leto izida:
Tipologija: 1.01 - Izvirni znanstveni članek
Organizacija: UM FKKT - Fakulteta za kemijo in kemijsko tehnologijo
UDK: 547
COBISS: 11727894 Povezava se bo odprla v novem oknu
ISSN: 0024-9297
Št. ogledov: 1858
Št. prenosov: 61
Ocena: 0 (0 glasov)
Metapodatki: JSON JSON-RDF JSON-LD TURTLE N-TRIPLES XML RDFA MICRODATA DC-XML DC-RDF RDF

Ostali podatki

Sekundarni jezik: Angleški jezik
Sekundarne ključne besede: organska kemija;polimerizacija;monolitni polimeri;HIPE;emulzije;porozni materiali;metakrilati;
URN: URN:SI:UM:
Strani: str. 8056-8060
Letnik: ǂVol. ǂ40
Zvezek: ǂno ǂ22
Čas izdaje: 30. oct. 2007
ID: 8717408